Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate

In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl­aldehyde imine ligands, leading to a distorted tetra­hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intr...

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Autor principal: Hao, Yuan-Zeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257443/
https://www.ncbi.nlm.nih.gov/pubmed/25553004
http://dx.doi.org/10.1107/S1600536814022636
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author Hao, Yuan-Zeng
author_facet Hao, Yuan-Zeng
author_sort Hao, Yuan-Zeng
collection PubMed
description In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl­aldehyde imine ligands, leading to a distorted tetra­hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra­molecular non-classical C—H⋯O hydrogen-bonding inter­actions are observed. In the crystal, the complex mol­ecules stack into columns along the a axis. Di­chloro­methane solvent mol­ecules are situated in the voids of this arrangement.
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spelling pubmed-42574432014-12-31 Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate Hao, Yuan-Zeng Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, [Zn(C(18)H(28)NO)(2)]·CH(2)Cl(2), the Zn(II) atom is N,O-chelated by two crystallographically independent salicyl­aldehyde imine ligands, leading to a distorted tetra­hedral coordination sphere. The dihedral angle between the planes of the two metallacycles is 88.69 (6)°. Intra­molecular non-classical C—H⋯O hydrogen-bonding inter­actions are observed. In the crystal, the complex mol­ecules stack into columns along the a axis. Di­chloro­methane solvent mol­ecules are situated in the voids of this arrangement. International Union of Crystallography 2014-11-05 /pmc/articles/PMC4257443/ /pubmed/25553004 http://dx.doi.org/10.1107/S1600536814022636 Text en © Yuan-Zeng Hao 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Hao, Yuan-Zeng
Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate
title Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate
title_full Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate
title_fullStr Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate
title_full_unstemmed Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate
title_short Crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) N,O}zinc di­chloro­methane mono­solvate
title_sort crystal structure of bis­{2,4-di-tert-butyl-6-[(iso­propyl­imino)­meth­yl]phenolato-κ(2) n,o}zinc di­chloro­methane mono­solvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257443/
https://www.ncbi.nlm.nih.gov/pubmed/25553004
http://dx.doi.org/10.1107/S1600536814022636
work_keys_str_mv AT haoyuanzeng crystalstructureofbis24ditertbutyl6isopropyliminomethylphenolatok2nozincdichloromethanemonosolvate

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