Crystal structure of propaquizafop

The title compound, C(22)H(22)ClN(3)O(5) {systematic name: 2-(propan-2-yl­idene­amino­oxy)ethyl (R)-2-[4-(6-chloro­quin­oxalin-2-yl­oxy)phen­oxy]propionate}, is a herbicide. The asymmetric unit comprises two independent mol­ecules in which the dihedral angles between the phenyl ring and the quinoxal...

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Detalles Bibliográficos
Autores principales: Jeon, Youngeun, Kim, Jineun, Lee, Sangjin, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257450/
https://www.ncbi.nlm.nih.gov/pubmed/25553037
http://dx.doi.org/10.1107/S1600536814024751
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author Jeon, Youngeun
Kim, Jineun
Lee, Sangjin
Kim, Tae Ho
author_facet Jeon, Youngeun
Kim, Jineun
Lee, Sangjin
Kim, Tae Ho
author_sort Jeon, Youngeun
collection PubMed
description The title compound, C(22)H(22)ClN(3)O(5) {systematic name: 2-(propan-2-yl­idene­amino­oxy)ethyl (R)-2-[4-(6-chloro­quin­oxalin-2-yl­oxy)phen­oxy]propionate}, is a herbicide. The asymmetric unit comprises two independent mol­ecules in which the dihedral angles between the phenyl ring and the quinoxaline ring plane are 75.93 (7) and 82.77 (8)°. The crystal structure features C—H⋯O, C—H⋯N, and C—H⋯Cl hydrogen bonds, as well as weak π–π inter­actions [ring-centroid separation = 3.782 (2) and 3.5952 (19) Å], resulting in a three-dimensional architecture.
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spelling pubmed-42574502014-12-31 Crystal structure of propaquizafop Jeon, Youngeun Kim, Jineun Lee, Sangjin Kim, Tae Ho Acta Crystallogr Sect E Struct Rep Online Data Reports The title compound, C(22)H(22)ClN(3)O(5) {systematic name: 2-(propan-2-yl­idene­amino­oxy)ethyl (R)-2-[4-(6-chloro­quin­oxalin-2-yl­oxy)phen­oxy]propionate}, is a herbicide. The asymmetric unit comprises two independent mol­ecules in which the dihedral angles between the phenyl ring and the quinoxaline ring plane are 75.93 (7) and 82.77 (8)°. The crystal structure features C—H⋯O, C—H⋯N, and C—H⋯Cl hydrogen bonds, as well as weak π–π inter­actions [ring-centroid separation = 3.782 (2) and 3.5952 (19) Å], resulting in a three-dimensional architecture. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257450/ /pubmed/25553037 http://dx.doi.org/10.1107/S1600536814024751 Text en © Jeon et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Jeon, Youngeun
Kim, Jineun
Lee, Sangjin
Kim, Tae Ho
Crystal structure of propaquizafop
title Crystal structure of propaquizafop
title_full Crystal structure of propaquizafop
title_fullStr Crystal structure of propaquizafop
title_full_unstemmed Crystal structure of propaquizafop
title_short Crystal structure of propaquizafop
title_sort crystal structure of propaquizafop
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257450/
https://www.ncbi.nlm.nih.gov/pubmed/25553037
http://dx.doi.org/10.1107/S1600536814024751
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AT kimjineun crystalstructureofpropaquizafop
AT leesangjin crystalstructureofpropaquizafop
AT kimtaeho crystalstructureofpropaquizafop

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