Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)

The asymmetric unit of the title salt, [C(22)H(20)O(2)P](2) (+)[TeI(6)](2−), consists of one triphenyl(5-oxooxolan-3-yl)phosphanium cation and one half of a hexa­iodido­tellurate(IV) dianion. The Te atom is located at an inversion centre and is octa­hedrally coordinated by six I atoms. The Te—I bond...

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Detalles Bibliográficos
Autores principales: Närhi, Sari M., Oilunkaniemi, Raija, Laitinen, Risto S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257451/
https://www.ncbi.nlm.nih.gov/pubmed/25553021
http://dx.doi.org/10.1107/S1600536814023940
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author Närhi, Sari M.
Oilunkaniemi, Raija
Laitinen, Risto S.
author_facet Närhi, Sari M.
Oilunkaniemi, Raija
Laitinen, Risto S.
author_sort Närhi, Sari M.
collection PubMed
description The asymmetric unit of the title salt, [C(22)H(20)O(2)P](2) (+)[TeI(6)](2−), consists of one triphenyl(5-oxooxolan-3-yl)phosphanium cation and one half of a hexa­iodido­tellurate(IV) dianion. The Te atom is located at an inversion centre and is octa­hedrally coordinated by six I atoms. The Te—I bond lengths range from 2.9255 (9) to 2.9439 (10) Å. The I—Te—I angles between cis-iodide ligands are in the range 87.85 (3)–92.15 (3)°. In the crystal, the components are connected by C—H⋯I inter­actions. In the final refinement of the compound a void of 32 Å(3) was observed.
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spelling pubmed-42574512014-12-31 Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV) Närhi, Sari M. Oilunkaniemi, Raija Laitinen, Risto S. Acta Crystallogr Sect E Struct Rep Online Data Reports The asymmetric unit of the title salt, [C(22)H(20)O(2)P](2) (+)[TeI(6)](2−), consists of one triphenyl(5-oxooxolan-3-yl)phosphanium cation and one half of a hexa­iodido­tellurate(IV) dianion. The Te atom is located at an inversion centre and is octa­hedrally coordinated by six I atoms. The Te—I bond lengths range from 2.9255 (9) to 2.9439 (10) Å. The I—Te—I angles between cis-iodide ligands are in the range 87.85 (3)–92.15 (3)°. In the crystal, the components are connected by C—H⋯I inter­actions. In the final refinement of the compound a void of 32 Å(3) was observed. International Union of Crystallography 2014-11-05 /pmc/articles/PMC4257451/ /pubmed/25553021 http://dx.doi.org/10.1107/S1600536814023940 Text en © Närhi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Närhi, Sari M.
Oilunkaniemi, Raija
Laitinen, Risto S.
Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)
title Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)
title_full Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)
title_fullStr Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)
title_full_unstemmed Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)
title_short Crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(IV)
title_sort crystal structure of bis­[(5-oxo­oxolan-3-yl)triphen­ylphosphanium] hexa­iodido­tellurate(iv)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257451/
https://www.ncbi.nlm.nih.gov/pubmed/25553021
http://dx.doi.org/10.1107/S1600536814023940
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AT laitinenristos crystalstructureofbis5oxooxolan3yltriphenylphosphaniumhexaiodidotellurateiv

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