Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine

In the title compound, C(24)H(22)Br(2)N(2)S, the dihedral angles between the central pyrimidine ring and the pendant bromo­benzene rings are 11.02 (11) and 13.20 (12)°. The butyl side chain adopts a gauche conformation [C—C—C—C = −67.4 (4)°]. In the crystal, weak aromatic π–π stacking is observed be...

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Detalles Bibliográficos
Autores principales: Yu, Wang, Song, Jingbao, Wang, Aijian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257452/
https://www.ncbi.nlm.nih.gov/pubmed/25553047
http://dx.doi.org/10.1107/S1600536814024714
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author Yu, Wang
Song, Jingbao
Wang, Aijian
author_facet Yu, Wang
Song, Jingbao
Wang, Aijian
author_sort Yu, Wang
collection PubMed
description In the title compound, C(24)H(22)Br(2)N(2)S, the dihedral angles between the central pyrimidine ring and the pendant bromo­benzene rings are 11.02 (11) and 13.20 (12)°. The butyl side chain adopts a gauche conformation [C—C—C—C = −67.4 (4)°]. In the crystal, weak aromatic π–π stacking is observed between the pyrimidine ring and one of the benzene rings [centroid–centroid separation = 3.6718 (17) Å].
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spelling pubmed-42574522014-12-31 Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine Yu, Wang Song, Jingbao Wang, Aijian Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(24)H(22)Br(2)N(2)S, the dihedral angles between the central pyrimidine ring and the pendant bromo­benzene rings are 11.02 (11) and 13.20 (12)°. The butyl side chain adopts a gauche conformation [C—C—C—C = −67.4 (4)°]. In the crystal, weak aromatic π–π stacking is observed between the pyrimidine ring and one of the benzene rings [centroid–centroid separation = 3.6718 (17) Å]. International Union of Crystallography 2014-11-21 /pmc/articles/PMC4257452/ /pubmed/25553047 http://dx.doi.org/10.1107/S1600536814024714 Text en © Yu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Yu, Wang
Song, Jingbao
Wang, Aijian
Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
title Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
title_full Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
title_fullStr Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
title_full_unstemmed Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
title_short Crystal structure of 4,6-bis­[(E)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
title_sort crystal structure of 4,6-bis­[(e)-4-bromo­styr­yl]-2-(butyl­sulfan­yl)pyrimidine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257452/
https://www.ncbi.nlm.nih.gov/pubmed/25553047
http://dx.doi.org/10.1107/S1600536814024714
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