Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]

In the crystal structure of the title compound, [Cd(NCS)(2)(C(9)H(13)N)(2)](n), the Cd(II) cations are coordinated in a slightly distorted octa­hedral geometry by one 3-tert-butyl­pyridine ligand, one 4-tert-butyl­pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio­cyanat...

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Detalles Bibliográficos
Autores principales: Werner, Julia, Reinert, Thorben, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257453/
https://www.ncbi.nlm.nih.gov/pubmed/25553011
http://dx.doi.org/10.1107/S1600536814024647
Descripción
Sumario:In the crystal structure of the title compound, [Cd(NCS)(2)(C(9)H(13)N)(2)](n), the Cd(II) cations are coordinated in a slightly distorted octa­hedral geometry by one 3-tert-butyl­pyridine ligand, one 4-tert-butyl­pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio­cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio­cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.

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