Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]

In the crystal structure of the title compound, [Cd(NCS)(2)(C(9)H(13)N)(2)](n), the Cd(II) cations are coordinated in a slightly distorted octa­hedral geometry by one 3-tert-butyl­pyridine ligand, one 4-tert-butyl­pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio­cyanat...

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Detalles Bibliográficos
Autores principales: Werner, Julia, Reinert, Thorben, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257453/
https://www.ncbi.nlm.nih.gov/pubmed/25553011
http://dx.doi.org/10.1107/S1600536814024647
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author Werner, Julia
Reinert, Thorben
Jess, Inke
Näther, Christian
author_facet Werner, Julia
Reinert, Thorben
Jess, Inke
Näther, Christian
author_sort Werner, Julia
collection PubMed
description In the crystal structure of the title compound, [Cd(NCS)(2)(C(9)H(13)N)(2)](n), the Cd(II) cations are coordinated in a slightly distorted octa­hedral geometry by one 3-tert-butyl­pyridine ligand, one 4-tert-butyl­pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio­cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio­cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis.
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spelling pubmed-42574532014-12-31 Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N] Werner, Julia Reinert, Thorben Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Data Reports In the crystal structure of the title compound, [Cd(NCS)(2)(C(9)H(13)N)(2)](n), the Cd(II) cations are coordinated in a slightly distorted octa­hedral geometry by one 3-tert-butyl­pyridine ligand, one 4-tert-butyl­pyridine ligand and two pairs of translationally-equivalent μ-1,3-bridging thio­cyanate ligands, all of which are in general positions. These μ-1,3-bridging thio­cyante anions bridge the Cd(II) cations, forming chains that propagate parallel to the b axis. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257453/ /pubmed/25553011 http://dx.doi.org/10.1107/S1600536814024647 Text en © Werner et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Werner, Julia
Reinert, Thorben
Jess, Inke
Näther, Christian
Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_fullStr Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_full_unstemmed Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_short Crystal structure of catena-poly[[(3-tert-butyl­pyridine-κN)(4-tert-butyl­pyridine-κN)cadmium]-di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N]
title_sort crystal structure of catena-poly[[(3-tert-butyl­pyridine-κn)(4-tert-butyl­pyridine-κn)cadmium]-di-μ-thio­cyanato-κ(2) n:s;κ(2) s:n]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257453/
https://www.ncbi.nlm.nih.gov/pubmed/25553011
http://dx.doi.org/10.1107/S1600536814024647
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