Cargando…

Crystal structure of methyl 1-methyl-3,5-diphenyl-7-tosyl-3,6,7,11b-tetra­hydro­pyrazolo­[4′,3′:5,6]pyrano[3,4-c]quinoline-5a(5H)-carboxyl­ate

In the title compound, C(35)H(31)N(3)O(5)S, the piperidine ring adopts an envelope conformation, with the methine C atom as the flap, and the pyran ring adopts a sofa conformation. The mean planes of these two rings are almost normal to one another, making a dihedral angle of 85.96 (5)°. The two phe...

Descripción completa

Detalles Bibliográficos
Autores principales: Nadendla, Eswar Kumar, Jagadeesan, G., Kannan, D., Bakthadoss, Mannickam, Gunasekaran, K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257454/
https://www.ncbi.nlm.nih.gov/pubmed/25553055
http://dx.doi.org/10.1107/S160053681402515X
Descripción
Sumario:In the title compound, C(35)H(31)N(3)O(5)S, the piperidine ring adopts an envelope conformation, with the methine C atom as the flap, and the pyran ring adopts a sofa conformation. The mean planes of these two rings are almost normal to one another, making a dihedral angle of 85.96 (5)°. The two phenyl rings, one attached to the pyrazole ring and the other to the pyran ring, are inclined to one another by 65.41 (11)°. They are inclined to the mean planes of the rings to which they are attached by 12.59 (11) and 70.09 (9)°, respectively. There is an intra­molecular C—H⋯π inter­action involving the tosyl­ate methyl group and the phenyl ring attached to the pyrazole ring. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming ribbons parallel to (10-2). The ribbons are linked by slipped parallel π–π inter­actions involving inversion-related pyrazole rings [inter-centroid distance = 3.672 (2) Å], forming slabs parallel to (001). A preliminary report of this structure has been published [Bakthadoss et al. (2014 ▶). Eur. J. Org. Chem. pp. 1505–1513].