Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide

The title mol­ecular salt, C(13)H(15)N(2) (+)·Br(−), crystallized with two independent ion pairs (A and B) in the asymmetric unit. In the cations, the planes of the pyridine and benzene rings are inclined to one another by 79.32 (8) and 82.30 (10)° in ion pairs A and B, respectively. In the crystal,...

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Autores principales: Sharmila, N., Sundar, T. V., Yasodha, A., Puratchikody, A., Sridhar, B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257457/
https://www.ncbi.nlm.nih.gov/pubmed/25553054
http://dx.doi.org/10.1107/S1600536814025343
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author Sharmila, N.
Sundar, T. V.
Yasodha, A.
Puratchikody, A.
Sridhar, B.
author_facet Sharmila, N.
Sundar, T. V.
Yasodha, A.
Puratchikody, A.
Sridhar, B.
author_sort Sharmila, N.
collection PubMed
description The title mol­ecular salt, C(13)H(15)N(2) (+)·Br(−), crystallized with two independent ion pairs (A and B) in the asymmetric unit. In the cations, the planes of the pyridine and benzene rings are inclined to one another by 79.32 (8) and 82.30 (10)° in ion pairs A and B, respectively. In the crystal, the anions and cations are connected by N—H⋯Br hydrogen bonds, forming a centrosymmetric tetra­mer-like unit enclosing an R (8) (4)(16) ring motif. These units are linked via C—H⋯Br hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-42574572014-12-31 Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide Sharmila, N. Sundar, T. V. Yasodha, A. Puratchikody, A. Sridhar, B. Acta Crystallogr Sect E Struct Rep Online Data Reports The title mol­ecular salt, C(13)H(15)N(2) (+)·Br(−), crystallized with two independent ion pairs (A and B) in the asymmetric unit. In the cations, the planes of the pyridine and benzene rings are inclined to one another by 79.32 (8) and 82.30 (10)° in ion pairs A and B, respectively. In the crystal, the anions and cations are connected by N—H⋯Br hydrogen bonds, forming a centrosymmetric tetra­mer-like unit enclosing an R (8) (4)(16) ring motif. These units are linked via C—H⋯Br hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2014-11-26 /pmc/articles/PMC4257457/ /pubmed/25553054 http://dx.doi.org/10.1107/S1600536814025343 Text en © Sharmila et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sharmila, N.
Sundar, T. V.
Yasodha, A.
Puratchikody, A.
Sridhar, B.
Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
title Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
title_full Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
title_fullStr Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
title_full_unstemmed Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
title_short Crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
title_sort crystal structure of 4-amino-1-(4-methyl­benz­yl)pyridinium bromide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257457/
https://www.ncbi.nlm.nih.gov/pubmed/25553054
http://dx.doi.org/10.1107/S1600536814025343
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