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Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one

In the title compound, C(24)H(14)Cl(2)N(2)O(2)S, the 2H-chromene ring system is approximately planar, with a maximum deviation of 0.025 (2) Å. The thia­zole ring is almost planar, with an r.m.s. deviation of 0.0022 Å, and makes a dihedral angle of 58.52 (7)° with the chromene ring system. The chrome...

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Autores principales: Kayalvizhi, M., Vasuki, G., Kumar, R. Raj, Rao, V. Rajeswar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257461/
https://www.ncbi.nlm.nih.gov/pubmed/25553038
http://dx.doi.org/10.1107/S1600536814024775
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author Kayalvizhi, M.
Vasuki, G.
Kumar, R. Raj
Rao, V. Rajeswar
author_facet Kayalvizhi, M.
Vasuki, G.
Kumar, R. Raj
Rao, V. Rajeswar
author_sort Kayalvizhi, M.
collection PubMed
description In the title compound, C(24)H(14)Cl(2)N(2)O(2)S, the 2H-chromene ring system is approximately planar, with a maximum deviation of 0.025 (2) Å. The thia­zole ring is almost planar, with an r.m.s. deviation of 0.0022 Å, and makes a dihedral angle of 58.52 (7)° with the chromene ring system. The chromene ring system is inclined at angles of 58.3 (1) and 55.39 (9)° with respect to the two chloro­phenyl rings. The two chloro­phenyl rings show significant deviation from coplanarity, with a dihedral angle between them of 47.69 (8)°. The crystal structure features C—H⋯Cl inter­actions extending in (100) and propagating along the a-axis direction and weak π–π inter­actions [centroid–centroid separation = 3.867 (2) Å].
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spelling pubmed-42574612014-12-31 Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one Kayalvizhi, M. Vasuki, G. Kumar, R. Raj Rao, V. Rajeswar Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(24)H(14)Cl(2)N(2)O(2)S, the 2H-chromene ring system is approximately planar, with a maximum deviation of 0.025 (2) Å. The thia­zole ring is almost planar, with an r.m.s. deviation of 0.0022 Å, and makes a dihedral angle of 58.52 (7)° with the chromene ring system. The chromene ring system is inclined at angles of 58.3 (1) and 55.39 (9)° with respect to the two chloro­phenyl rings. The two chloro­phenyl rings show significant deviation from coplanarity, with a dihedral angle between them of 47.69 (8)°. The crystal structure features C—H⋯Cl inter­actions extending in (100) and propagating along the a-axis direction and weak π–π inter­actions [centroid–centroid separation = 3.867 (2) Å]. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257461/ /pubmed/25553038 http://dx.doi.org/10.1107/S1600536814024775 Text en © Kayalvizhi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kayalvizhi, M.
Vasuki, G.
Kumar, R. Raj
Rao, V. Rajeswar
Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one
title Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one
title_full Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one
title_fullStr Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one
title_full_unstemmed Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one
title_short Crystal structure of (Z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2H-chromen-2-one
title_sort crystal structure of (z)-3-{3-(4-chloro­phen­yl)-2-[(4-chloro­phen­yl)imino]-2,3-di­hydro­thia­zol-4-yl}-2h-chromen-2-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257461/
https://www.ncbi.nlm.nih.gov/pubmed/25553038
http://dx.doi.org/10.1107/S1600536814024775
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