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Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one
In the title compound, C(24)H(14)Cl(2)N(2)O(2)S, the 2H-chromene ring system is approximately planar, with a maximum deviation of 0.025 (2) Å. The thiazole ring is almost planar, with an r.m.s. deviation of 0.0022 Å, and makes a dihedral angle of 58.52 (7)° with the chromene ring system. The chrome...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257461/ https://www.ncbi.nlm.nih.gov/pubmed/25553038 http://dx.doi.org/10.1107/S1600536814024775 |
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author | Kayalvizhi, M. Vasuki, G. Kumar, R. Raj Rao, V. Rajeswar |
author_facet | Kayalvizhi, M. Vasuki, G. Kumar, R. Raj Rao, V. Rajeswar |
author_sort | Kayalvizhi, M. |
collection | PubMed |
description | In the title compound, C(24)H(14)Cl(2)N(2)O(2)S, the 2H-chromene ring system is approximately planar, with a maximum deviation of 0.025 (2) Å. The thiazole ring is almost planar, with an r.m.s. deviation of 0.0022 Å, and makes a dihedral angle of 58.52 (7)° with the chromene ring system. The chromene ring system is inclined at angles of 58.3 (1) and 55.39 (9)° with respect to the two chlorophenyl rings. The two chlorophenyl rings show significant deviation from coplanarity, with a dihedral angle between them of 47.69 (8)°. The crystal structure features C—H⋯Cl interactions extending in (100) and propagating along the a-axis direction and weak π–π interactions [centroid–centroid separation = 3.867 (2) Å]. |
format | Online Article Text |
id | pubmed-4257461 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42574612014-12-31 Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one Kayalvizhi, M. Vasuki, G. Kumar, R. Raj Rao, V. Rajeswar Acta Crystallogr Sect E Struct Rep Online Data Reports In the title compound, C(24)H(14)Cl(2)N(2)O(2)S, the 2H-chromene ring system is approximately planar, with a maximum deviation of 0.025 (2) Å. The thiazole ring is almost planar, with an r.m.s. deviation of 0.0022 Å, and makes a dihedral angle of 58.52 (7)° with the chromene ring system. The chromene ring system is inclined at angles of 58.3 (1) and 55.39 (9)° with respect to the two chlorophenyl rings. The two chlorophenyl rings show significant deviation from coplanarity, with a dihedral angle between them of 47.69 (8)°. The crystal structure features C—H⋯Cl interactions extending in (100) and propagating along the a-axis direction and weak π–π interactions [centroid–centroid separation = 3.867 (2) Å]. International Union of Crystallography 2014-11-19 /pmc/articles/PMC4257461/ /pubmed/25553038 http://dx.doi.org/10.1107/S1600536814024775 Text en © Kayalvizhi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Kayalvizhi, M. Vasuki, G. Kumar, R. Raj Rao, V. Rajeswar Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one |
title | Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one |
title_full | Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one |
title_fullStr | Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one |
title_full_unstemmed | Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one |
title_short | Crystal structure of (Z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2H-chromen-2-one |
title_sort | crystal structure of (z)-3-{3-(4-chlorophenyl)-2-[(4-chlorophenyl)imino]-2,3-dihydrothiazol-4-yl}-2h-chromen-2-one |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257461/ https://www.ncbi.nlm.nih.gov/pubmed/25553038 http://dx.doi.org/10.1107/S1600536814024775 |
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