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Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate)
In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendicular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two ind...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257463/ https://www.ncbi.nlm.nih.gov/pubmed/25553001 http://dx.doi.org/10.1107/S1600536814025756 |
Sumario: | In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendicular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 82.7 (5) and 85.5 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into the inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagating along the b-axis direction. Weak C—H⋯π interactions are observed between neighbouring chains. |
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