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Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)

In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendic­ular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two ind...

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Detalles Bibliográficos
Autores principales: Lu, Xin-Hua, Sun, Hong-Shun, Hu, Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257463/
https://www.ncbi.nlm.nih.gov/pubmed/25553001
http://dx.doi.org/10.1107/S1600536814025756
Descripción
Sumario:In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendic­ular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 82.7 (5) and 85.5 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into the inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supra­molecular chains propagating along the b-axis direction. Weak C—H⋯π inter­actions are observed between neighbouring chains.