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Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)

In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendic­ular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two ind...

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Detalles Bibliográficos
Autores principales: Lu, Xin-Hua, Sun, Hong-Shun, Hu, Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257463/
https://www.ncbi.nlm.nih.gov/pubmed/25553001
http://dx.doi.org/10.1107/S1600536814025756
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author Lu, Xin-Hua
Sun, Hong-Shun
Hu, Jin
author_facet Lu, Xin-Hua
Sun, Hong-Shun
Hu, Jin
author_sort Lu, Xin-Hua
collection PubMed
description In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendic­ular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 82.7 (5) and 85.5 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into the inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supra­molecular chains propagating along the b-axis direction. Weak C—H⋯π inter­actions are observed between neighbouring chains.
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spelling pubmed-42574632014-12-31 Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate) Lu, Xin-Hua Sun, Hong-Shun Hu, Jin Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendic­ular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 82.7 (5) and 85.5 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the mol­ecules into the inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supra­molecular chains propagating along the b-axis direction. Weak C—H⋯π inter­actions are observed between neighbouring chains. International Union of Crystallography 2014-11-29 /pmc/articles/PMC4257463/ /pubmed/25553001 http://dx.doi.org/10.1107/S1600536814025756 Text en © Lu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Lu, Xin-Hua
Sun, Hong-Shun
Hu, Jin
Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_full Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_fullStr Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_full_unstemmed Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_short Crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1H-indole-2-carboxyl­ate)
title_sort crystal structure of dimethyl 3,3′-[(3-fluoro­phenyl)methyl­ene]bis­(1h-indole-2-carboxyl­ate)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257463/
https://www.ncbi.nlm.nih.gov/pubmed/25553001
http://dx.doi.org/10.1107/S1600536814025756
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