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Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate)
In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendicular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two ind...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257463/ https://www.ncbi.nlm.nih.gov/pubmed/25553001 http://dx.doi.org/10.1107/S1600536814025756 |
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author | Lu, Xin-Hua Sun, Hong-Shun Hu, Jin |
author_facet | Lu, Xin-Hua Sun, Hong-Shun Hu, Jin |
author_sort | Lu, Xin-Hua |
collection | PubMed |
description | In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendicular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 82.7 (5) and 85.5 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into the inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagating along the b-axis direction. Weak C—H⋯π interactions are observed between neighbouring chains. |
format | Online Article Text |
id | pubmed-4257463 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-42574632014-12-31 Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) Lu, Xin-Hua Sun, Hong-Shun Hu, Jin Acta Crystallogr Sect E Struct Rep Online Research Communications In the title compound, C(27)H(21)FN(2)O(4), the mean planes of the two indole ring systems (r.m.s. deviations = 0.0166 and 0.0086 Å) are approximately perpendicular to one another, making a dihedral angle of 87.8 (5)°; the fluorobenzene ring is twisted with respect to the mean planes of the two indole ring systems at 82.7 (5) and 85.5 (3)°. In the crystal, pairs of N—H⋯O hydrogen bonds link the molecules into the inversion dimers, which are further linked by N—H⋯O hydrogen bonds into supramolecular chains propagating along the b-axis direction. Weak C—H⋯π interactions are observed between neighbouring chains. International Union of Crystallography 2014-11-29 /pmc/articles/PMC4257463/ /pubmed/25553001 http://dx.doi.org/10.1107/S1600536814025756 Text en © Lu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Lu, Xin-Hua Sun, Hong-Shun Hu, Jin Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title | Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_full | Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_fullStr | Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_full_unstemmed | Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_short | Crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1H-indole-2-carboxylate) |
title_sort | crystal structure of dimethyl 3,3′-[(3-fluorophenyl)methylene]bis(1h-indole-2-carboxylate) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257463/ https://www.ncbi.nlm.nih.gov/pubmed/25553001 http://dx.doi.org/10.1107/S1600536814025756 |
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