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Metal-Free Dihydrogen Oxidation by a Borenium Cation: A Combined Electrochemical/Frustrated Lewis Pair Approach**
In order to use H(2) as a clean source of electricity, prohibitively rare and expensive precious metal electrocatalysts, such as Pt, are often used to overcome the large oxidative voltage required to convert H(2) into 2 H(+) and 2 e(−). Herein, we report a metal-free approach to catalyze the oxidati...
Autores principales: | Lawrence, Elliot J, Herrington, Thomas J, Ashley, Andrew E, Wildgoose, Gregory G |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
WILEY-VCH Verlag
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4257500/ https://www.ncbi.nlm.nih.gov/pubmed/25044562 http://dx.doi.org/10.1002/anie.201405721 |
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