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Irreversible Catalyst Activation Enables Hyperpolarization and Water Solubility for NMR Signal Amplification by Reversible Exchange

[Image: see text] Activation of a catalyst [IrCl(COD)(IMes)] (IMes = 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; COD = cyclooctadiene)] for signal amplification by reversible exchange (SABRE) was monitored by in situ hyperpolarized proton NMR at 9.4 T. During the catalyst-activation process, t...

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Detalles Bibliográficos
Autores principales:	Truong, Milton L., Shi, Fan, He, Ping, Yuan, Bingxin, Plunkett, Kyle N., Coffey, Aaron M., Shchepin, Roman V., Barskiy, Danila A., Kovtunov, Kirill V., Koptyug, Igor V., Waddell, Kevin W., Goodson, Boyd M., Chekmenev, Eduard Y.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4259498/ https://www.ncbi.nlm.nih.gov/pubmed/25372972 http://dx.doi.org/10.1021/jp510825b

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