Facile Formation of β-Hydroxyboronate Esters by a Cu-Catalyzed Diboration/Matteson Homologation Sequence

[Image: see text] The copper-catalyzed diboration of aldehydes was used in conjunction with the Matteson homologation, providing the efficient synthesis of β-hydroxyboronate esters. The oxygen-bound boronate ester was found to play a key role in mediating the homologation reaction, which was compare...

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Detalles Bibliográficos
Autores principales: Moore, Cameron M., Medina, Casey R., Cannamela, Peter C., McIntosh, Melissa L., Ferber, Carl J., Roering, Andrew J., Clark, Timothy B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4260635/
https://www.ncbi.nlm.nih.gov/pubmed/25412356
http://dx.doi.org/10.1021/ol502767m

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