Cargando…

Copper-Catalyzed Oxidative Homo- and Cross-Coupling of Grignard Reagents Using Diaziridinone

[Image: see text] Transition-metal-catalyzed cross-coupling reactions are among the most powerful synthetic transformations. This paper describes an efficient copper-catalyzed homo- and cross-coupling of Grignard reagents with di-tert-butyldiaziridinone as oxidant under mild conditions, giving the c...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zhu, Yingguang, Xiong, Tao, Han, Wenyong, Shi, Yian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4260645/ https://www.ncbi.nlm.nih.gov/pubmed/25420218 http://dx.doi.org/10.1021/ol5030103

Ejemplares similares

Iron‐catalyzed Cross‐Coupling of Propargyl Carboxylates and Grignard Reagents: Synthesis of Substituted Allenes
por: Kessler, Simon N., et al.
Publicado: (2016)

Grignard Reagent-Catalyzed Hydroboration of Esters, Nitriles, and Imines
por: Han, Hyun Ji, et al.
Publicado: (2023)

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Benzylic Ethers with Isotopically-Labeled Grignard Reagents
por: Dawson, David D., et al.
Publicado: (2015)

Iron‐Catalyzed Cross‐Coupling of Alkynyl and Styrenyl Chlorides with Alkyl Grignard Reagents in Batch and Flow
por: Deng, Yuchao, et al.
Publicado: (2019)

Iron‐Catalyzed Cross‐Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols
por: Posevins, Daniels, et al.
Publicado: (2021)

Copper‐Catalyzed Addition of Grignard Reagents to in situ Generated Indole‐Derived Vinylogous Imines
por: Ge, Luo, et al.
Publicado: (2020)

Pd-catalyzed allylative dearomatisation using Grignard reagents
por: Boldrini, Cosimo, et al.
Publicado: (2021)

Cross-Coupling Reaction of Allylic Ethers with Aryl Grignard Reagents Catalyzed by a Nickel Pincer Complex
por: Hashimoto, Toru, et al.
Publicado: (2019)

Iron-Catalyzed Cross-Coupling of α-Allenyl Esters with Grignard Reagents for the Synthesis of 1,3-Dienes
por: Kong, Wei-Jun, et al.
Publicado: (2023)

A Synthesis of Substituted α-Allenols via Iron-Catalyzed Cross-Coupling of Propargyl Carboxylates with Grignard Reagents
por: Kessler, Simon N., et al.
Publicado: (2016)

Iron-Catalyzed Coupling of Aryl Grignard Reagents with Alkyl Halides: A Competitive Hammett Study**
por: Hedström, Anna, et al.
Publicado: (2011)

Cobalt-Catalyzed (Hetero)arylation of Saturated Cyclic Amines with Grignard Reagents
por: Barré, Baptiste, et al.
Publicado: (2018)

Iron-Catalyzed C(sp(2))–C(sp(3)) Cross-Coupling of Aryl Chlorobenzoates with Alkyl Grignard Reagents
por: Bisz, Elwira, et al.
Publicado: (2020)

Copper-Free Alternatives to Access Ketone Building Blocks from Grignard Reagents
por: Taeschler, Christoph, et al.
Publicado: (2022)

Tertiary amine synthesis via reductive coupling of amides with Grignard reagents
por: Xie, Lan-Gui, et al.
Publicado: (2017)

Iron-Catalyzed Cross-Coupling Reactions of Alkyl Grignards with Aryl Chlorobenzenesulfonates
por: Bisz, Elwira
Publicado: (2021)

Fe-catalyzed three-component dicarbofunctionalization of unactivated alkenes with alkyl halides and Grignard reagents
por: Liu, Lei, et al.
Publicado: (2020)

Nickel-catalyzed coupling reaction of alkyl halides with aryl Grignard reagents in the presence of 1,3-butadiene: mechanistic studies of four-component coupling and competing cross-coupling reactions
por: Iwasaki, Takanori, et al.
Publicado: (2018)

Conjugate Addition of Grignard Reagents to Thiochromones Catalyzed by Copper Salts: A Unified Approach to Both 2-Alkylthiochroman-4-One and Thioflavanone
por: Bellinger, Tania J., et al.
Publicado: (2020)

Copper(I)-Catalyzed Cross-Coupling of 1-Bromoalkynes with N-Heterocyclic Organozinc Reagents
por: Frabitore, Christian, et al.
Publicado: (2022)

Catalytic enantioselective addition of Grignard reagents to aromatic silyl ketimines
por: Rong, Jiawei, et al.
Publicado: (2016)

Investigation of Grignard Reagent as an Advanced Base for Aza-Claisen Rearrangement
por: Song, Bo Reum, et al.
Publicado: (2019)

Synthesis of Bis-heteroaryls Using Grignard Reagents and Pyridylsulfonium Salts
por: Horan, Alexandra M., et al.
Publicado: (2021)

Halogenation Reactions of Alkyl Alcohols Employing Methyl Grignard Reagents
por: Hirbawi, Nadia, et al.
Publicado: (2022)

Hypervalent Iodine Reagents in Palladium-Catalyzed Oxidative Cross-Coupling Reactions
por: Shetgaonkar, Samata E., et al.
Publicado: (2020)

A DFT Study on Fe(I)/Fe(II)/Fe(III) Mechanism of the Cross-Coupling between Haloalkane and Aryl Grignard Reagent Catalyzed by Iron-SciOPP Complexes
por: Sharma, Akhilesh K., et al.
Publicado: (2020)

Unusual Nucleophilic Addition of Grignard Reagents in the Synthesis of 4-Amino-pyrimidines
por: Tinson, Ryan A. J., et al.
Publicado: (2018)

Highly Enantioselective Catalytic Addition of Grignard Reagents to N‐Heterocyclic Acceptors
por: Guo, Yafei, et al.
Publicado: (2019)

Enantioselective Catalytic Dearomative Addition of Grignard Reagents to 4-Methoxypyridinium Ions
por: Guo, Yafei, et al.
Publicado: (2021)

Morphological Plasticity of LiCl Clusters Interacting with Grignard Reagent in Tetrahydrofuran
por: de Giovanetti, Marinella, et al.
Publicado: (2023)

Iron‐Catalyzed Cross‐Coupling of Thioesters and Organomanganese Reagents
por: Geiger, Valentin Jacob, et al.
Publicado: (2022)

Kumada–Tamao–Corriu Type Reaction of Aromatic Bromo- and Iodoamines with Grignard Reagents
por: Zielińska, Alicja A., et al.
Publicado: (2023)

Ni/Co-Catalyzed Homo-Coupling of Alkyl Tosylates
por: Komeyama, Kimihiro, et al.
Publicado: (2019)

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent
por: Wang, Xiao-Ping, et al.
Publicado: (2013)

Copper-catalyzed arylation of alkyl halides with arylaluminum reagents
por: Shrestha, Bijay, et al.
Publicado: (2015)

Copper-catalyzed aminoalkynylation of alkenes with hypervalent iodine reagents
por: Shen, Kun, et al.
Publicado: (2017)

Kumada–Grignard-type biaryl couplings on water
por: Bhattacharjya, Anish, et al.
Publicado: (2015)

Continuous flow synthesis of diaryl ketones by coupling of aryl Grignard reagents with acyl chlorides under mild conditions in the ecofriendly solvent 2-methyltetrahydrofuran
por: Zhang, Chuan-Tao, et al.
Publicado: (2019)

Non-Palladium-Catalyzed Oxidative Coupling Reactions Using Hypervalent Iodine Reagents
por: Shetgaonkar, Samata E., et al.
Publicado: (2022)

Sequential olefination–dimerisation of benzylic dithioacetals by the nickel-catalysed reaction with methyl Grignard or zinc reagent
por: Yu, Lei, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_elo38qfndn1rpaim6nhd5redj0