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Synthesis of Ordered Mesoporous Phenanthrenequinone-Carbon via π-π Interaction-Dependent Vapor Pressure for Rechargeable Batteries

The π-π interaction-dependent vapour pressure of phenanthrenequinone can be used to synthesize a phenanthrenequinone-confined ordered mesoporous carbon. Intimate contact between the insulating phenanthrenequinone and the conductive carbon framework improves the electrical conductivity. This enables...

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Detalles Bibliográficos
Autores principales: Kwon, Mi-Sook, Choi, Aram, Park, Yuwon, Cheon, Jae Yeong, Kang, Hyojin, Jo, Yong Nam, Kim, Young-Jun, Hong, Sung You, Joo, Sang Hoon, Yang, Changduk, Lee, Kyu Tae
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4261180/
https://www.ncbi.nlm.nih.gov/pubmed/25490893
http://dx.doi.org/10.1038/srep07404
Descripción
Sumario:The π-π interaction-dependent vapour pressure of phenanthrenequinone can be used to synthesize a phenanthrenequinone-confined ordered mesoporous carbon. Intimate contact between the insulating phenanthrenequinone and the conductive carbon framework improves the electrical conductivity. This enables a more complete redox reaction take place. The confinement of the phenanthrenequinone in the mesoporous carbon mitigates the diffusion of the dissolved phenanthrenequinone out of the mesoporous carbon, and improves cycling performance.