Functional Conducting Polymers via Thiol-ene Chemistry

We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished th...

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Detalles Bibliográficos
Autores principales: Feldman, Kathleen E., Martin, David C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2012
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4263549/
https://www.ncbi.nlm.nih.gov/pubmed/25585932
http://dx.doi.org/10.3390/bios2030305
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author Feldman, Kathleen E.
Martin, David C.
author_facet Feldman, Kathleen E.
Martin, David C.
author_sort Feldman, Kathleen E.
collection PubMed
description We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers.
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spelling pubmed-42635492015-01-13 Functional Conducting Polymers via Thiol-ene Chemistry Feldman, Kathleen E. Martin, David C. Biosensors (Basel) Article We demonstrate here that thiol-ene chemistry can be used to provide side-chain functionalized monomers based on 3,4-propylenedioxythiophene (ProDOT) containing ionic, neutral, hydrophobic, and hydrophilic side chains. All reactions gave high yields and purification could generally be accomplished through precipitation. These monomers were polymerized either chemically or electro-chemically to give soluble materials or conductive films, respectively. This strategy provides for facile tuning of the solubility, film surface chemistry, and film morphology of this class of conducting polymers. MDPI 2012-08-31 /pmc/articles/PMC4263549/ /pubmed/25585932 http://dx.doi.org/10.3390/bios2030305 Text en © 2012 by the authors; licensee MDPI, Basel, Switzerland. http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Feldman, Kathleen E.
Martin, David C.
Functional Conducting Polymers via Thiol-ene Chemistry
title Functional Conducting Polymers via Thiol-ene Chemistry
title_full Functional Conducting Polymers via Thiol-ene Chemistry
title_fullStr Functional Conducting Polymers via Thiol-ene Chemistry
title_full_unstemmed Functional Conducting Polymers via Thiol-ene Chemistry
title_short Functional Conducting Polymers via Thiol-ene Chemistry
title_sort functional conducting polymers via thiol-ene chemistry
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4263549/
https://www.ncbi.nlm.nih.gov/pubmed/25585932
http://dx.doi.org/10.3390/bios2030305
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