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Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers

A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alken...

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Autores principales: Zhang, Jia-Xiang, Wang, Yan-Jing, Zhang, Wei, Wang, Nai-Xing, Bai, Cui-Bing, Xing, Ya-Lan, Li, Yi-He, Wen, Jia-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4264008/
https://www.ncbi.nlm.nih.gov/pubmed/25502282
http://dx.doi.org/10.1038/srep07446
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author Zhang, Jia-Xiang
Wang, Yan-Jing
Zhang, Wei
Wang, Nai-Xing
Bai, Cui-Bing
Xing, Ya-Lan
Li, Yi-He
Wen, Jia-Long
author_facet Zhang, Jia-Xiang
Wang, Yan-Jing
Zhang, Wei
Wang, Nai-Xing
Bai, Cui-Bing
Xing, Ya-Lan
Li, Yi-He
Wen, Jia-Long
author_sort Zhang, Jia-Xiang
collection PubMed
description A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alkenylation.
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spelling pubmed-42640082014-12-16 Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers Zhang, Jia-Xiang Wang, Yan-Jing Zhang, Wei Wang, Nai-Xing Bai, Cui-Bing Xing, Ya-Lan Li, Yi-He Wen, Jia-Long Sci Rep Article A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alkenylation. Nature Publishing Group 2014-12-12 /pmc/articles/PMC4264008/ /pubmed/25502282 http://dx.doi.org/10.1038/srep07446 Text en Copyright © 2014, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-nd/4.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder in order to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/4.0/
spellingShingle Article
Zhang, Jia-Xiang
Wang, Yan-Jing
Zhang, Wei
Wang, Nai-Xing
Bai, Cui-Bing
Xing, Ya-Lan
Li, Yi-He
Wen, Jia-Long
Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
title Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
title_full Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
title_fullStr Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
title_full_unstemmed Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
title_short Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
title_sort selective nickel- and manganese-catalyzed decarboxylative cross coupling of some α,β-unsaturated carboxylic acids with cyclic ethers
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4264008/
https://www.ncbi.nlm.nih.gov/pubmed/25502282
http://dx.doi.org/10.1038/srep07446
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