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Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alken...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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Nature Publishing Group
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4264008/ https://www.ncbi.nlm.nih.gov/pubmed/25502282 http://dx.doi.org/10.1038/srep07446 |
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author | Zhang, Jia-Xiang Wang, Yan-Jing Zhang, Wei Wang, Nai-Xing Bai, Cui-Bing Xing, Ya-Lan Li, Yi-He Wen, Jia-Long |
author_facet | Zhang, Jia-Xiang Wang, Yan-Jing Zhang, Wei Wang, Nai-Xing Bai, Cui-Bing Xing, Ya-Lan Li, Yi-He Wen, Jia-Long |
author_sort | Zhang, Jia-Xiang |
collection | PubMed |
description | A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alkenylation. |
format | Online Article Text |
id | pubmed-4264008 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | Nature Publishing Group |
record_format | MEDLINE/PubMed |
spelling | pubmed-42640082014-12-16 Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers Zhang, Jia-Xiang Wang, Yan-Jing Zhang, Wei Wang, Nai-Xing Bai, Cui-Bing Xing, Ya-Lan Li, Yi-He Wen, Jia-Long Sci Rep Article A nickel- and manganese-catalyzed decarboxylative cross coupling of α, β-unsaturated carboxylic acids with cyclic ethers such as tetrahydrofuran and 1, 4-dioxane was developed. Oxyalkylation was achieved when nickel acetate was used as catalyst, while manganese acetate promoted the reaction of alkenylation. Nature Publishing Group 2014-12-12 /pmc/articles/PMC4264008/ /pubmed/25502282 http://dx.doi.org/10.1038/srep07446 Text en Copyright © 2014, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-nd/4.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder in order to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-nd/4.0/ |
spellingShingle | Article Zhang, Jia-Xiang Wang, Yan-Jing Zhang, Wei Wang, Nai-Xing Bai, Cui-Bing Xing, Ya-Lan Li, Yi-He Wen, Jia-Long Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers |
title | Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers |
title_full | Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers |
title_fullStr | Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers |
title_full_unstemmed | Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers |
title_short | Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers |
title_sort | selective nickel- and manganese-catalyzed decarboxylative cross coupling of some α,β-unsaturated carboxylic acids with cyclic ethers |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4264008/ https://www.ncbi.nlm.nih.gov/pubmed/25502282 http://dx.doi.org/10.1038/srep07446 |
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