Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand

[Image: see text] The three-coordinate imidos (dtbpe)Ni=NR (dtbpe = (t)Bu(2)PCH(2)CH(2)P(t)Bu(2,) R = 2,6-(i)Pr(2)C(6)H(3), 2,4,6-Me(3)C(6)H(2) (Mes), and 1-adamantyl (Ad)), which contain a legitimate Ni–N double bond as well as basic imido nitrogen based on theoretical analysis, readily deprotonate...

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Detalles Bibliográficos
Autores principales: Mindiola, Daniel J., Waterman, Rory, Iluc, Vlad M., Cundari, Thomas R., Hillhouse, Gregory L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4269405/
https://www.ncbi.nlm.nih.gov/pubmed/25437507
http://dx.doi.org/10.1021/ic5026153

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4269405/
https://www.ncbi.nlm.nih.gov/pubmed/25437507
http://dx.doi.org/10.1021/ic5026153

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