Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)

C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.

Detalles Bibliográficos
Autores principales: Adamkiewicz, Malgorzata, O’Hagan, David, Hähner, Georg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273226/
https://www.ncbi.nlm.nih.gov/pubmed/25550756
http://dx.doi.org/10.3762/bjoc.10.307
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author Adamkiewicz, Malgorzata
O’Hagan, David
Hähner, Georg
author_facet Adamkiewicz, Malgorzata
O’Hagan, David
Hähner, Georg
author_sort Adamkiewicz, Malgorzata
collection PubMed
description C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage.
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spelling pubmed-42732262014-12-30 Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs) Adamkiewicz, Malgorzata O’Hagan, David Hähner, Georg Beilstein J Org Chem Full Research Paper C11-Vinyl-terminated self-assembled monolayers (SAMs) on silica surfaces are successfully modified in C–C bond forming reactions with dihalocarbenes to generate SAMs, terminated with dihalo- (fluoro, chloro, bromo) cyclopropane motifs with about 30% surface coverage. Beilstein-Institut 2014-12-05 /pmc/articles/PMC4273226/ /pubmed/25550756 http://dx.doi.org/10.3762/bjoc.10.307 Text en Copyright © 2014, Adamkiewicz et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Adamkiewicz, Malgorzata
O’Hagan, David
Hähner, Georg
Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_full Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_fullStr Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_full_unstemmed Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_short Organic chemistry on surfaces: Direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (SAMs)
title_sort organic chemistry on surfaces: direct cyclopropanation by dihalocarbene addition to vinyl terminated self-assembled monolayers (sams)
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273226/
https://www.ncbi.nlm.nih.gov/pubmed/25550756
http://dx.doi.org/10.3762/bjoc.10.307
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