Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis

New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combi...

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Detalles Bibliográficos
Autores principales: Potier, Jonathan, Menuel, Stéphane, Mathiron, David, Bonnet, Véronique, Hapiot, Frédéric, Monflier, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273264/
https://www.ncbi.nlm.nih.gov/pubmed/25550725
http://dx.doi.org/10.3762/bjoc.10.276
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author Potier, Jonathan
Menuel, Stéphane
Mathiron, David
Bonnet, Véronique
Hapiot, Frédéric
Monflier, Eric
author_facet Potier, Jonathan
Menuel, Stéphane
Mathiron, David
Bonnet, Véronique
Hapiot, Frédéric
Monflier, Eric
author_sort Potier, Jonathan
collection PubMed
description New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities.
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spelling pubmed-42732642014-12-30 Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis Potier, Jonathan Menuel, Stéphane Mathiron, David Bonnet, Véronique Hapiot, Frédéric Monflier, Eric Beilstein J Org Chem Letter New cyclodextrin (CD)-grafted polymers functionalized with water-soluble phosphanes were synthesized in three steps starting from polyNAS. Once characterized by NMR spectroscopy and size-exclusion chromatography, they were used as additives in Rh-catalyzed hydroformylation of 1-hexadecene. The combined supramolecular and coordinating properties of these polymers allowed increasing the catalytic activity of the reaction without affecting the selectivities. Beilstein-Institut 2014-11-11 /pmc/articles/PMC4273264/ /pubmed/25550725 http://dx.doi.org/10.3762/bjoc.10.276 Text en Copyright © 2014, Potier et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Potier, Jonathan
Menuel, Stéphane
Mathiron, David
Bonnet, Véronique
Hapiot, Frédéric
Monflier, Eric
Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
title Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
title_full Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
title_fullStr Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
title_full_unstemmed Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
title_short Cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
title_sort cyclodextrin-grafted polymers functionalized with phosphanes: a new tool for aqueous organometallic catalysis
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273264/
https://www.ncbi.nlm.nih.gov/pubmed/25550725
http://dx.doi.org/10.3762/bjoc.10.276
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