Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction

Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolcular [1,5]-hydride shift/isomerization reaction has been realized, using the inherent reducing power of 3-pyrrolines. A series of N-arylpyrrole containing amines are obtained in high yields.

Detalles Bibliográficos
Autores principales: Jiang, Chun-Huan, Lei, Xiantao, Zhen, Le, Du, Hong-Jin, Wen, Xiaoan, Xu, Qing-Long, Sun, Hongbin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273273/
https://www.ncbi.nlm.nih.gov/pubmed/25550755
http://dx.doi.org/10.3762/bjoc.10.306
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author Jiang, Chun-Huan
Lei, Xiantao
Zhen, Le
Du, Hong-Jin
Wen, Xiaoan
Xu, Qing-Long
Sun, Hongbin
author_facet Jiang, Chun-Huan
Lei, Xiantao
Zhen, Le
Du, Hong-Jin
Wen, Xiaoan
Xu, Qing-Long
Sun, Hongbin
author_sort Jiang, Chun-Huan
collection PubMed
description Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolcular [1,5]-hydride shift/isomerization reaction has been realized, using the inherent reducing power of 3-pyrrolines. A series of N-arylpyrrole containing amines are obtained in high yields.
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spelling pubmed-42732732014-12-30 Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction Jiang, Chun-Huan Lei, Xiantao Zhen, Le Du, Hong-Jin Wen, Xiaoan Xu, Qing-Long Sun, Hongbin Beilstein J Org Chem Full Research Paper Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolcular [1,5]-hydride shift/isomerization reaction has been realized, using the inherent reducing power of 3-pyrrolines. A series of N-arylpyrrole containing amines are obtained in high yields. Beilstein-Institut 2014-12-05 /pmc/articles/PMC4273273/ /pubmed/25550755 http://dx.doi.org/10.3762/bjoc.10.306 Text en Copyright © 2014, Jiang et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Jiang, Chun-Huan
Lei, Xiantao
Zhen, Le
Du, Hong-Jin
Wen, Xiaoan
Xu, Qing-Long
Sun, Hongbin
Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
title Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
title_full Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
title_fullStr Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
title_full_unstemmed Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
title_short Lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
title_sort lewis acid-catalyzed redox-neutral amination of 2-(3-pyrroline-1-yl)benzaldehydes via intramolecular [1,5]-hydride shift/isomerization reaction
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273273/
https://www.ncbi.nlm.nih.gov/pubmed/25550755
http://dx.doi.org/10.3762/bjoc.10.306
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