Synthesis and properties of novel star-shaped oligofluorene conjugated systems with BODIPY cores

Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1–T-B4 and Y-B1–Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption...

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Detalles Bibliográficos
Autores principales: Orofino-Pena, Clara, Cortizo-Lacalle, Diego, Cameron, Joseph, Sajjad, Muhammad T, Manousiadis, Pavlos P, Findlay, Neil J, Kanibolotsky, Alexander L, Amarasinghe, Dimali, Skabara, Peter J, Tuttle, Tell, Turnbull, Graham A, Samuel, Ifor D W
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273294/
https://www.ncbi.nlm.nih.gov/pubmed/25550734
http://dx.doi.org/10.3762/bjoc.10.285
Descripción
Sumario:Star-shaped conjugated systems with varying oligofluorene arm length and substitution patterns of the central BODIPY core have been synthesised, leading to two families of compounds, T-B1–T-B4 and Y-B1–Y-B4, with T- and Y-shaped motifs, respectively. Thermal stability, cyclic voltammetry, absorption and photoluminescence spectroscopy of each member of these two families were studied in order to determine their suitability as emissive materials in photonic applications.

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