Cargando…

Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS

The blue triangle nanosilver (BAgNP) sol was prepared by the two reducers of NaBH(4) and H(2)O(2). Using BAgNP as the precursor, a small spherical nanosilver (AgNP) sol in yellow was synthesized by addition of suitable amounts of X(−) (X = Cl, Br, and I). The oxidization process of BAgNP to AgNP was...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Qingye, Wen, Guiqing, Zhang, Xinghui, Liang, Aihui, Jiang, Zhiliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273675/
https://www.ncbi.nlm.nih.gov/pubmed/25593553
http://dx.doi.org/10.1186/1556-276X-9-663
_version_ 1782349873991909376
author Liu, Qingye
Wen, Guiqing
Zhang, Xinghui
Liang, Aihui
Jiang, Zhiliang
author_facet Liu, Qingye
Wen, Guiqing
Zhang, Xinghui
Liang, Aihui
Jiang, Zhiliang
author_sort Liu, Qingye
collection PubMed
description The blue triangle nanosilver (BAgNP) sol was prepared by the two reducers of NaBH(4) and H(2)O(2). Using BAgNP as the precursor, a small spherical nanosilver (AgNP) sol in yellow was synthesized by addition of suitable amounts of X(−) (X = Cl, Br, and I). The oxidization process of BAgNP to AgNP was studied in detail by resonance Rayleigh scattering (RRS), surface-enhanced Raman scattering (SERS), laser scattering, surface plasmon resonance (SPR) absorption, and microscope techniques. It has been observed that NaCl accelerated the oxidizing BAgNP to form AgNP, and an oxidizing mechanism and quasi-nanograting Raman-scattering enhanced mechanism were developed to explain the phenomena. Using the BAgNP sol as substrate and based on the catalysis of Ti(IV) on the BrO(3)(−) oxidizing safranine T (ST) molecular probe with a strong SERS peak at 1,535 cm(−1), a new catalytic SERS quantitative method was developed for the determination of 1.0 to 100 ng/mL Ti, with a detection limit of 0.4 ng/mL.
format Online
Article
Text
id pubmed-4273675
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher Springer
record_format MEDLINE/PubMed
spelling pubmed-42736752015-01-15 Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS Liu, Qingye Wen, Guiqing Zhang, Xinghui Liang, Aihui Jiang, Zhiliang Nanoscale Res Lett Nano Express The blue triangle nanosilver (BAgNP) sol was prepared by the two reducers of NaBH(4) and H(2)O(2). Using BAgNP as the precursor, a small spherical nanosilver (AgNP) sol in yellow was synthesized by addition of suitable amounts of X(−) (X = Cl, Br, and I). The oxidization process of BAgNP to AgNP was studied in detail by resonance Rayleigh scattering (RRS), surface-enhanced Raman scattering (SERS), laser scattering, surface plasmon resonance (SPR) absorption, and microscope techniques. It has been observed that NaCl accelerated the oxidizing BAgNP to form AgNP, and an oxidizing mechanism and quasi-nanograting Raman-scattering enhanced mechanism were developed to explain the phenomena. Using the BAgNP sol as substrate and based on the catalysis of Ti(IV) on the BrO(3)(−) oxidizing safranine T (ST) molecular probe with a strong SERS peak at 1,535 cm(−1), a new catalytic SERS quantitative method was developed for the determination of 1.0 to 100 ng/mL Ti, with a detection limit of 0.4 ng/mL. Springer 2014-12-10 /pmc/articles/PMC4273675/ /pubmed/25593553 http://dx.doi.org/10.1186/1556-276X-9-663 Text en Copyright © 2014 Liu et al.; licensee Springer. http://creativecommons.org/licenses/by/4.0 This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.
spellingShingle Nano Express
Liu, Qingye
Wen, Guiqing
Zhang, Xinghui
Liang, Aihui
Jiang, Zhiliang
Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS
title Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS
title_full Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS
title_fullStr Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS
title_full_unstemmed Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS
title_short Utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by SERS
title_sort utilization of triangle nanosilver to prepare spherical nanosilver and quantitatively detect trace titanium by sers
topic Nano Express
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4273675/
https://www.ncbi.nlm.nih.gov/pubmed/25593553
http://dx.doi.org/10.1186/1556-276X-9-663
work_keys_str_mv AT liuqingye utilizationoftrianglenanosilvertopreparesphericalnanosilverandquantitativelydetecttracetitaniumbysers
AT wenguiqing utilizationoftrianglenanosilvertopreparesphericalnanosilverandquantitativelydetecttracetitaniumbysers
AT zhangxinghui utilizationoftrianglenanosilvertopreparesphericalnanosilverandquantitativelydetecttracetitaniumbysers
AT liangaihui utilizationoftrianglenanosilvertopreparesphericalnanosilverandquantitativelydetecttracetitaniumbysers
AT jiangzhiliang utilizationoftrianglenanosilvertopreparesphericalnanosilverandquantitativelydetecttracetitaniumbysers