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Mechanism, Reactivity, and Selectivity of Nickel-Catalyzed [4 + 4 + 2] Cycloadditions of Dienes and Alkynes

[Image: see text] Density functional theory (DFT) calculations with B3LYP and M06 functionals elucidated the reactivities of alkynes and Z/E selectivity of cyclodecatriene products in the Ni-catalyzed [4 + 4 + 2] cycloadditions of dienes and alkynes. The Ni-mediated oxidative cyclization of butadien...

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Detalles Bibliográficos
Autores principales:	Hong, Xin, Holte, Dane, Götz, Daniel C. G., Baran, Phil S., Houk, K. N.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4275152/ https://www.ncbi.nlm.nih.gov/pubmed/25325891 http://dx.doi.org/10.1021/jo502219d

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