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Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P(4) Inverted Sandwich Compounds
[Image: see text] We report the synthesis and comprehensive study of the electronic structure of a unique series of dinuclear group 5 cyclo-tetraphosphide inverted sandwich complexes. White phosphorus (P(4)) reacts with niobium(III) and tantalum(III) β-diketiminate (BDI) tert-butylimido complexes to...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277768/ https://www.ncbi.nlm.nih.gov/pubmed/25469924 http://dx.doi.org/10.1021/ja5107282 |