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Activation of White Phosphorus by Low-Valent Group 5 Complexes: Formation and Reactivity of cyclo-P(4) Inverted Sandwich Compounds

[Image: see text] We report the synthesis and comprehensive study of the electronic structure of a unique series of dinuclear group 5 cyclo-tetraphosphide inverted sandwich complexes. White phosphorus (P(4)) reacts with niobium(III) and tantalum(III) β-diketiminate (BDI) tert-butylimido complexes to...

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Detalles Bibliográficos
Autores principales:	Camp, Clément, Maron, Laurent, Bergman, Robert G., Arnold, John
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277768/ https://www.ncbi.nlm.nih.gov/pubmed/25469924 http://dx.doi.org/10.1021/ja5107282

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