Simple, Chemoselective, Catalytic Olefin Isomerization

[Image: see text] Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile function...

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Autores principales: Crossley, Steven W. M., Barabé, Francis, Shenvi, Ryan A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277770/
https://www.ncbi.nlm.nih.gov/pubmed/25398144
http://dx.doi.org/10.1021/ja5105602
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author Crossley, Steven W. M.
Barabé, Francis
Shenvi, Ryan A.
author_facet Crossley, Steven W. M.
Barabé, Francis
Shenvi, Ryan A.
author_sort Crossley, Steven W. M.
collection PubMed
description [Image: see text] Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
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spelling pubmed-42777702015-11-14 Simple, Chemoselective, Catalytic Olefin Isomerization Crossley, Steven W. M. Barabé, Francis Shenvi, Ryan A. J Am Chem Soc [Image: see text] Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated. American Chemical Society 2014-11-14 2014-12-03 /pmc/articles/PMC4277770/ /pubmed/25398144 http://dx.doi.org/10.1021/ja5105602 Text en Copyright © 2014 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Crossley, Steven W. M.
Barabé, Francis
Shenvi, Ryan A.
Simple, Chemoselective, Catalytic Olefin Isomerization
title Simple, Chemoselective, Catalytic Olefin Isomerization
title_full Simple, Chemoselective, Catalytic Olefin Isomerization
title_fullStr Simple, Chemoselective, Catalytic Olefin Isomerization
title_full_unstemmed Simple, Chemoselective, Catalytic Olefin Isomerization
title_short Simple, Chemoselective, Catalytic Olefin Isomerization
title_sort simple, chemoselective, catalytic olefin isomerization
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277770/
https://www.ncbi.nlm.nih.gov/pubmed/25398144
http://dx.doi.org/10.1021/ja5105602
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