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Alkali Metal Control over N–N Cleavage in Iron Complexes

[Image: see text] Though N(2) cleavage on K-promoted Fe surfaces is important in the large-scale Haber–Bosch process, there is still ambiguity about the number of Fe atoms involved during the N–N cleaving step and the interactions responsible for the promoting ability of K. This work explores a mole...

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Detalles Bibliográficos
Autores principales: Grubel, Katarzyna, Brennessel, William W., Mercado, Brandon Q., Holland, Patrick L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4277784/
https://www.ncbi.nlm.nih.gov/pubmed/25412468
http://dx.doi.org/10.1021/ja507442b