The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity

The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P(4), and their intriguing follow-up chemistry are highlighted. In addition, this re...

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Detalles Bibliográficos
Autores principales: Holthausen, Michael H., Weigand, Jan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4288811/
https://www.ncbi.nlm.nih.gov/pubmed/24740160
http://dx.doi.org/10.1039/c4cs00019f
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author Holthausen, Michael H.
Weigand, Jan J.
author_facet Holthausen, Michael H.
Weigand, Jan J.
author_sort Holthausen, Michael H.
collection PubMed
description The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P(4), and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P(4) and its transformation into (organo-)phosphorus compounds and materials of added value.
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spelling pubmed-42888112015-01-26 The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity Holthausen, Michael H. Weigand, Jan J. Chem Soc Rev Chemistry The aim of this review is to provide a comprehensive view of the chemistry of cationic polyphosphorus cages. The synthetic protocols established for their preparation, which are all based on the functionalization of P(4), and their intriguing follow-up chemistry are highlighted. In addition, this review intends to foster the interest of the inorganic, organic, catalytic and material oriented chemical communities in the versatile field of polyphosphorus cage compounds. In the long term, this is envisioned to contribute to the development of new synthetic procedures for the functionalization of P(4) and its transformation into (organo-)phosphorus compounds and materials of added value. Royal Society of Chemistry 2014-09-21 2014-04-17 /pmc/articles/PMC4288811/ /pubmed/24740160 http://dx.doi.org/10.1039/c4cs00019f Text en This journal is © The Royal Society of Chemistry 2014 http://creativecommons.org/licenses/by/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 Unported License (http://creativecommons.org/licenses/by/3.0/) which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Holthausen, Michael H.
Weigand, Jan J.
The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
title The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
title_full The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
title_fullStr The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
title_full_unstemmed The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
title_short The chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
title_sort chemistry of cationic polyphosphorus cages – syntheses, structure and reactivity
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4288811/
https://www.ncbi.nlm.nih.gov/pubmed/24740160
http://dx.doi.org/10.1039/c4cs00019f
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