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Endo-Selective Pd-Catalyzed Silyl Methyl Heck Reaction
[Image: see text] A palladium (Pd)-catalyzed endo-selective Heck reaction of iodomethylsilyl ethers of phenols and aliphatic alkenols has been developed. Mechanistic studies reveal that this silyl methyl Heck reaction operates via a hybrid Pd-radical process and that the silicon atom is crucial for...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291758/ https://www.ncbi.nlm.nih.gov/pubmed/25494921 http://dx.doi.org/10.1021/ja5104525 |