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Mechanism of the Reduction of the Native Intermediate in the Multicopper Oxidases: Insights into Rapid Intramolecular Electron Transfer in Turnover
[Image: see text] The multicopper oxidases (MCOs) are the family of enzymes that catalyze the 4-electron reduction of O(2) to H(2)O coupled to the four 1-electron oxidations of substrate. In the catalytic cycle electrons are transferred intramolecularly over ∼13 Å from a Type 1 (T1) Cu site that acc...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291763/ https://www.ncbi.nlm.nih.gov/pubmed/25490729 http://dx.doi.org/10.1021/ja509150j |