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Resonant Inelastic X-ray Scattering on Ferrous and Ferric Bis-imidazole Porphyrin and Cytochrome c: Nature and Role of the Axial Methionine–Fe Bond

[Image: see text] Axial Cu–S(Met) bonds in electron transfer (ET) active sites are generally found to lower their reduction potentials. An axial S(Met) bond is also present in cytochrome c (cyt c) and is generally thought to increase the reduction potential. The highly covalent nature of the porphyr...

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Detalles Bibliográficos
Autores principales:	Kroll, Thomas, Hadt, Ryan G., Wilson, Samuel A., Lundberg, Marcus, Yan, James J., Weng, Tsu-Chien, Sokaras, Dimosthenis, Alonso-Mori, Roberto, Casa, Diego, Upton, Mary H., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4291809/ https://www.ncbi.nlm.nih.gov/pubmed/25475739 http://dx.doi.org/10.1021/ja5100367

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