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Comprehensive Fe–Ligand Vibration Identification in {FeNO}(6) Hemes

[Image: see text] Oriented single-crystal nuclear resonance vibrational spectroscopy (NRVS) has been used to obtain all iron vibrations in two {FeNO}(6) porphyrinate complexes, five-coordinate [Fe(OEP)(NO)]ClO(4) and six-coordinate [Fe(OEP)(2-MeHIm)(NO)]ClO(4). A new crystal structure was required f...

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Detalles Bibliográficos
Autores principales: Li, Jianfeng, Peng, Qian, Oliver, Allen G., Alp, E. Ercan, Hu, Michael Y., Zhao, Jiyong, Sage, J. Timothy, Scheidt, W. Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4295236/
https://www.ncbi.nlm.nih.gov/pubmed/25490350
http://dx.doi.org/10.1021/ja5105766