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Phosphonate–Phosphinate Rearrangement

[Image: see text] LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH(3)O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–p...

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Detalles Bibliográficos
Autores principales:	Qian, Renzhe, Roller, Alexander, Hammerschmidt, Friedrich
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2014
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4301053/ https://www.ncbi.nlm.nih.gov/pubmed/25525945 http://dx.doi.org/10.1021/jo502567j

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