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One-step hydrothermal synthesis of graphene decorated V(2)O(5) nanobelts for enhanced electrochemical energy storage

Graphene-decorated V(2)O(5) nanobelts (GVNBs) were synthesized via a low-temperature hydrothermal method in a single step. V(2)O(5) nanobelts (VNBs) were formed in the presence of graphene oxide, a mild oxidant, which also enhanced the conductivity of GVNBs. From the electron energy loss spectroscop...

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Detalles Bibliográficos
Autores principales: Lee, Minoh, Balasingam, Suresh Kannan, Jeong, Hu Young, Hong, Won G., Lee, Han-Bo-Ram, Kim, Byung Hoon, Jun, Yongseok
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311251/
https://www.ncbi.nlm.nih.gov/pubmed/25633147
http://dx.doi.org/10.1038/srep08151
Descripción
Sumario:Graphene-decorated V(2)O(5) nanobelts (GVNBs) were synthesized via a low-temperature hydrothermal method in a single step. V(2)O(5) nanobelts (VNBs) were formed in the presence of graphene oxide, a mild oxidant, which also enhanced the conductivity of GVNBs. From the electron energy loss spectroscopy analysis, the reduced graphene oxide (rGO) are inserted into the layered crystal structure of V(2)O(5) nanobelts, which further confirmed the enhanced conductivity of the nanobelts. The electrochemical energy-storage capacity of GVNBs was investigated for supercapacitor applications. The specific capacitance of GVNBs was evaluated using cyclic voltammetry (CV) and charge/discharge (CD) studies. The GVNBs having V(2)O(5)-rich composite, namely, V(3)G(1) (VO/GO = 3:1), showed superior specific capacitance in comparison to the other composites (V(1)G(1) and V(1)G(3)) and the pure materials. Moreover, the V(3)G(1) composite showed excellent cyclic stability and the capacitance retention of about 82% was observed even after 5000 cycles.