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Metal-Catalyzed Azidation of Tertiary C–H Bonds Suitable for Late-Stage Functionalization
Some enzymes are able to selectively oxidize unactivated aliphatic C-H bonds to form alcohols; however biological systems do not possess enzymes that are able to catalyze the analogous amination of a C-H bond.(1,2) The absence of such chemistry is limiting because nitrogen-containing groups are foun...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311404/ https://www.ncbi.nlm.nih.gov/pubmed/25631448 http://dx.doi.org/10.1038/nature14127 |