A carbohydrate approach for the formal total synthesis of (−)-aspergillide C

An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.

Detalles Bibliográficos
Autores principales: Srihari, Pabbaraja, Hari Krishna, Namballa, Sridhar, Ydhyam, Kamal, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311580/
https://www.ncbi.nlm.nih.gov/pubmed/25670981
http://dx.doi.org/10.3762/bjoc.10.329
Descripción
Sumario:An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.

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