A carbohydrate approach for the formal total synthesis of (−)-aspergillide C

An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.

Detalles Bibliográficos
Autores principales: Srihari, Pabbaraja, Hari Krishna, Namballa, Sridhar, Ydhyam, Kamal, Ahmed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311580/
https://www.ncbi.nlm.nih.gov/pubmed/25670981
http://dx.doi.org/10.3762/bjoc.10.329
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author Srihari, Pabbaraja
Hari Krishna, Namballa
Sridhar, Ydhyam
Kamal, Ahmed
author_facet Srihari, Pabbaraja
Hari Krishna, Namballa
Sridhar, Ydhyam
Kamal, Ahmed
author_sort Srihari, Pabbaraja
collection PubMed
description An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.
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spelling pubmed-43115802015-02-10 A carbohydrate approach for the formal total synthesis of (−)-aspergillide C Srihari, Pabbaraja Hari Krishna, Namballa Sridhar, Ydhyam Kamal, Ahmed Beilstein J Org Chem Letter An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions. Beilstein-Institut 2014-12-23 /pmc/articles/PMC4311580/ /pubmed/25670981 http://dx.doi.org/10.3762/bjoc.10.329 Text en Copyright © 2014, Srihari et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Srihari, Pabbaraja
Hari Krishna, Namballa
Sridhar, Ydhyam
Kamal, Ahmed
A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
title A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
title_full A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
title_fullStr A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
title_full_unstemmed A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
title_short A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
title_sort carbohydrate approach for the formal total synthesis of (−)-aspergillide c
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311580/
https://www.ncbi.nlm.nih.gov/pubmed/25670981
http://dx.doi.org/10.3762/bjoc.10.329
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