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A carbohydrate approach for the formal total synthesis of (−)-aspergillide C
An enantioselective formal total synthesis of aspergillide C is accomplished using commercially available tri-O-acetyl-D-galactal employing a Ferrier-type C-glycosylation, utilizing a Trost hydrosilylation and protodesilylation as key reactions.
Autores principales: | Srihari, Pabbaraja, Hari Krishna, Namballa, Sridhar, Ydhyam, Kamal, Ahmed |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311580/ https://www.ncbi.nlm.nih.gov/pubmed/25670981 http://dx.doi.org/10.3762/bjoc.10.329 |
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