Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans

A visible-light-induced photoredox-catalyzed bromoetherification of alkenols is described. This approach, with CBr(4) as the bromine source through generation of bromine in situ, provides a mild and operationally simple access to the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans with hi...

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Detalles Bibliográficos
Autores principales: Lin, Run, Sun, Hongnan, Yang, Chao, Yang, Youdong, Zhao, Xinxin, Xia, Wujiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311724/
https://www.ncbi.nlm.nih.gov/pubmed/25670989
http://dx.doi.org/10.3762/bjoc.11.5
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author Lin, Run
Sun, Hongnan
Yang, Chao
Yang, Youdong
Zhao, Xinxin
Xia, Wujiong
author_facet Lin, Run
Sun, Hongnan
Yang, Chao
Yang, Youdong
Zhao, Xinxin
Xia, Wujiong
author_sort Lin, Run
collection PubMed
description A visible-light-induced photoredox-catalyzed bromoetherification of alkenols is described. This approach, with CBr(4) as the bromine source through generation of bromine in situ, provides a mild and operationally simple access to the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans with high efficiency and regioselectivity.
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spelling pubmed-43117242015-02-10 Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans Lin, Run Sun, Hongnan Yang, Chao Yang, Youdong Zhao, Xinxin Xia, Wujiong Beilstein J Org Chem Full Research Paper A visible-light-induced photoredox-catalyzed bromoetherification of alkenols is described. This approach, with CBr(4) as the bromine source through generation of bromine in situ, provides a mild and operationally simple access to the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans with high efficiency and regioselectivity. Beilstein-Institut 2015-01-08 /pmc/articles/PMC4311724/ /pubmed/25670989 http://dx.doi.org/10.3762/bjoc.11.5 Text en Copyright © 2015, Lin et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Lin, Run
Sun, Hongnan
Yang, Chao
Yang, Youdong
Zhao, Xinxin
Xia, Wujiong
Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
title Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
title_full Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
title_fullStr Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
title_full_unstemmed Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
title_short Visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
title_sort visible-light-induced bromoetherification of alkenols for the synthesis of β-bromotetrahydrofurans and -tetrahydropyrans
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311724/
https://www.ncbi.nlm.nih.gov/pubmed/25670989
http://dx.doi.org/10.3762/bjoc.11.5
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