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Hydrogen Atom Abstraction from Hydrocarbons by a Copper(III)-Hydroxide Complex

[Image: see text] With the aim of understanding the basis for the high rate of hydrogen atom abstraction (HAT) from dihydroanthracene (DHA) by the complex LCuOH (1; L = N,N′-bis(2,6-diisopropylphenyl)-2,6-pyridinedicarboxamide), the bond dissociation enthalpy of the reaction product LCu(H(2)O) (2) w...

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Detalles Bibliográficos
Autores principales: Dhar, Debanjan, Tolman, William B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4311965/
https://www.ncbi.nlm.nih.gov/pubmed/25581555
http://dx.doi.org/10.1021/ja512014z