Modular chiral gold(i) phosphite complexes

Chiral gold(i) phosphite complexes are readily prepared modularly from 3,3′-bis(triphenylsilyl)-1,1′-bi-2-naphthol. These chiral gold(i) phosphite complexes are very reactive precatalysts for the [4+2] cycloaddition of aryl-substituted 1,6-enynes with enantiomeric ratios ranging from 86 : 14 up to 9...

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Autores principales: Delpont, Nicolas, Escofet, Imma, Pérez-Galán, Patricia, Spiegl, Dirk, Raducan, Mihai, Bour, Christophe, Sinisi, Riccardo, Echavarren, Antonio M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2013
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4317972/
https://www.ncbi.nlm.nih.gov/pubmed/25664164
http://dx.doi.org/10.1039/c3cy00250k
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author Delpont, Nicolas
Escofet, Imma
Pérez-Galán, Patricia
Spiegl, Dirk
Raducan, Mihai
Bour, Christophe
Sinisi, Riccardo
Echavarren, Antonio M.
author_facet Delpont, Nicolas
Escofet, Imma
Pérez-Galán, Patricia
Spiegl, Dirk
Raducan, Mihai
Bour, Christophe
Sinisi, Riccardo
Echavarren, Antonio M.
author_sort Delpont, Nicolas
collection PubMed
description Chiral gold(i) phosphite complexes are readily prepared modularly from 3,3′-bis(triphenylsilyl)-1,1′-bi-2-naphthol. These chiral gold(i) phosphite complexes are very reactive precatalysts for the [4+2] cycloaddition of aryl-substituted 1,6-enynes with enantiomeric ratios ranging from 86 : 14 up to 94 : 6.
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spelling pubmed-43179722015-02-06 Modular chiral gold(i) phosphite complexes Delpont, Nicolas Escofet, Imma Pérez-Galán, Patricia Spiegl, Dirk Raducan, Mihai Bour, Christophe Sinisi, Riccardo Echavarren, Antonio M. Catal Sci Technol Chemistry Chiral gold(i) phosphite complexes are readily prepared modularly from 3,3′-bis(triphenylsilyl)-1,1′-bi-2-naphthol. These chiral gold(i) phosphite complexes are very reactive precatalysts for the [4+2] cycloaddition of aryl-substituted 1,6-enynes with enantiomeric ratios ranging from 86 : 14 up to 94 : 6. Royal Society of Chemistry 2013-10-07 2013-07-22 /pmc/articles/PMC4317972/ /pubmed/25664164 http://dx.doi.org/10.1039/c3cy00250k Text en This journal is © The Royal Society of Chemistry 2013 http://creativecommons.org/licenses/by-nc/3.0/ This is an Open Access article distributed under the terms of the Creative Commons Attribution-NonCommercial 3.0 Unported License (http://creativecommons.org/licenses/by-nc/3.0/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Chemistry
Delpont, Nicolas
Escofet, Imma
Pérez-Galán, Patricia
Spiegl, Dirk
Raducan, Mihai
Bour, Christophe
Sinisi, Riccardo
Echavarren, Antonio M.
Modular chiral gold(i) phosphite complexes
title Modular chiral gold(i) phosphite complexes
title_full Modular chiral gold(i) phosphite complexes
title_fullStr Modular chiral gold(i) phosphite complexes
title_full_unstemmed Modular chiral gold(i) phosphite complexes
title_short Modular chiral gold(i) phosphite complexes
title_sort modular chiral gold(i) phosphite complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4317972/
https://www.ncbi.nlm.nih.gov/pubmed/25664164
http://dx.doi.org/10.1039/c3cy00250k
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