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Modular chiral gold(i) phosphite complexes

Chiral gold(i) phosphite complexes are readily prepared modularly from 3,3′-bis(triphenylsilyl)-1,1′-bi-2-naphthol. These chiral gold(i) phosphite complexes are very reactive precatalysts for the [4+2] cycloaddition of aryl-substituted 1,6-enynes with enantiomeric ratios ranging from 86 : 14 up to 9...

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Detalles Bibliográficos
Autores principales:	Delpont, Nicolas, Escofet, Imma, Pérez-Galán, Patricia, Spiegl, Dirk, Raducan, Mihai, Bour, Christophe, Sinisi, Riccardo, Echavarren, Antonio M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2013
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4317972/ https://www.ncbi.nlm.nih.gov/pubmed/25664164 http://dx.doi.org/10.1039/c3cy00250k

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