Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**

7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C(1) component of the cycloadditi...

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Detalles Bibliográficos
Autores principales: Wang, Yahui, Muratore, Michael E, Rong, Zhouting, Echavarren, Antonio M
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2014
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4320749/
https://www.ncbi.nlm.nih.gov/pubmed/24898850
http://dx.doi.org/10.1002/anie.201404029
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author Wang, Yahui
Muratore, Michael E
Rong, Zhouting
Echavarren, Antonio M
author_facet Wang, Yahui
Muratore, Michael E
Rong, Zhouting
Echavarren, Antonio M
author_sort Wang, Yahui
collection PubMed
description 7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C(1) component of the cycloaddition.
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spelling pubmed-43207492015-02-13 Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis** Wang, Yahui Muratore, Michael E Rong, Zhouting Echavarren, Antonio M Angew Chem Int Ed Engl Communications 7-Aryl-1,3,5-cycloheptatrienes react intermolecularly with methylenecyclopropanes in a triple gold(I)-catalyzed reaction to form cyclopentenes. The same formal (4+1) cycloaddition occurs with cyclobutenes. Other precursors of gold(I) carbenes can also be used as the C(1) component of the cycloaddition. WILEY-VCH Verlag 2014-12-15 2014-06-04 /pmc/articles/PMC4320749/ /pubmed/24898850 http://dx.doi.org/10.1002/anie.201404029 Text en © 2014 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. http://creativecommons.org/licenses/by/4.0/ This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Wang, Yahui
Muratore, Michael E
Rong, Zhouting
Echavarren, Antonio M
Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
title Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
title_full Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
title_fullStr Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
title_full_unstemmed Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
title_short Formal (4+1) Cycloaddition of Methylenecyclopropanes with 7-Aryl-1,3,5-cycloheptatrienes by Triple Gold(I) Catalysis**
title_sort formal (4+1) cycloaddition of methylenecyclopropanes with 7-aryl-1,3,5-cycloheptatrienes by triple gold(i) catalysis**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4320749/
https://www.ncbi.nlm.nih.gov/pubmed/24898850
http://dx.doi.org/10.1002/anie.201404029
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