Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate

In the cation of the title salt, C(6)H(7)N(2)S(+)·SCN(−), the C=S bond is oriented trans with respect to the C—C=N fragment in the pyridine ring. The planes of the aromatic ring and the thio­amide fragment of the cation make a dihedral angle of 38.31 (4)°. In the crystal, the components are linked b...

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Autores principales: Bouchareb, Hasna, Boudraa, Mhamed, Bouacida, Sofiane, Merazig, Hocine, Chtoun, El Hossain
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331844/
https://www.ncbi.nlm.nih.gov/pubmed/25705491
http://dx.doi.org/10.1107/S2056989014026437
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author Bouchareb, Hasna
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocine
Chtoun, El Hossain
author_facet Bouchareb, Hasna
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocine
Chtoun, El Hossain
author_sort Bouchareb, Hasna
collection PubMed
description In the cation of the title salt, C(6)H(7)N(2)S(+)·SCN(−), the C=S bond is oriented trans with respect to the C—C=N fragment in the pyridine ring. The planes of the aromatic ring and the thio­amide fragment of the cation make a dihedral angle of 38.31 (4)°. In the crystal, the components are linked by N—H⋯S and N—H⋯N, hydrogen bonds, forming a two-dimensional network parallel to (10-1).
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spelling pubmed-43318442015-02-20 Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate Bouchareb, Hasna Boudraa, Mhamed Bouacida, Sofiane Merazig, Hocine Chtoun, El Hossain Acta Crystallogr E Crystallogr Commun Data Reports In the cation of the title salt, C(6)H(7)N(2)S(+)·SCN(−), the C=S bond is oriented trans with respect to the C—C=N fragment in the pyridine ring. The planes of the aromatic ring and the thio­amide fragment of the cation make a dihedral angle of 38.31 (4)°. In the crystal, the components are linked by N—H⋯S and N—H⋯N, hydrogen bonds, forming a two-dimensional network parallel to (10-1). International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331844/ /pubmed/25705491 http://dx.doi.org/10.1107/S2056989014026437 Text en © Bouchareb et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Bouchareb, Hasna
Boudraa, Mhamed
Bouacida, Sofiane
Merazig, Hocine
Chtoun, El Hossain
Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
title Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
title_full Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
title_fullStr Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
title_full_unstemmed Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
title_short Crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
title_sort crystal structure of 3-carbamo­thio­yl­pyridinium thio­cyanate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331844/
https://www.ncbi.nlm.nih.gov/pubmed/25705491
http://dx.doi.org/10.1107/S2056989014026437
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AT merazighocine crystalstructureof3carbamothioylpyridiniumthiocyanate
AT chtounelhossain crystalstructureof3carbamothioylpyridiniumthiocyanate

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