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Crystal structure of 1-(4-methoxyphenyl)-4-(4-nitrophenyl)-3-phenoxyazetidin-2-one
In the title compound, C(22)H(18)N(2)O(5), the central β-lactam ring (r.m.s. deviation = 0.002 Å) makes dihedral angles of 64.21 (14), 82.35 (12) and 20.66 (13)° with the phenyl ring and the nitro- and methoxybenzene rings, respectively. The molecular structure is stabilized by an intramolecular...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331848/ https://www.ncbi.nlm.nih.gov/pubmed/25705479 http://dx.doi.org/10.1107/S2056989014025833 |
Sumario: | In the title compound, C(22)H(18)N(2)O(5), the central β-lactam ring (r.m.s. deviation = 0.002 Å) makes dihedral angles of 64.21 (14), 82.35 (12) and 20.66 (13)° with the phenyl ring and the nitro- and methoxybenzene rings, respectively. The molecular structure is stabilized by an intramolecular C—H⋯O hydrogen bond. In the crystal, molecules are linked via C—H⋯O hydrogen bonds, forming slabs lying parallel to (111). The slabs are linked via C—H⋯π interactions, forming a three-dimensional network. |
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