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Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one

In the title β-thio­carbonyl compound, C(16)H(16)O(2)S, the carbonyl and meth­oxy O atoms are approximately coplanar [O—C—C—O torsion angle = −18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. I...

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Autores principales: Zukerman-Schpector, Julio, Olivato, Paulo R., Traesel, Henrique J., Valença, Jéssica, Rodrigues, Daniel N. S., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331849/
https://www.ncbi.nlm.nih.gov/pubmed/25705490
http://dx.doi.org/10.1107/S205698901402550X
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author Zukerman-Schpector, Julio
Olivato, Paulo R.
Traesel, Henrique J.
Valença, Jéssica
Rodrigues, Daniel N. S.
Tiekink, Edward R. T.
author_facet Zukerman-Schpector, Julio
Olivato, Paulo R.
Traesel, Henrique J.
Valença, Jéssica
Rodrigues, Daniel N. S.
Tiekink, Edward R. T.
author_sort Zukerman-Schpector, Julio
collection PubMed
description In the title β-thio­carbonyl compound, C(16)H(16)O(2)S, the carbonyl and meth­oxy O atoms are approximately coplanar [O—C—C—O torsion angle = −18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In the crystal, supra­molecular chains are formed along the c axis mediated by C—H⋯O inter­actions involving methine and methyl H atoms as donors, with the carbonyl O atom accepting both bonds; these pack with no specific inter­molecular inter­actions between them.
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spelling pubmed-43318492015-02-20 Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one Zukerman-Schpector, Julio Olivato, Paulo R. Traesel, Henrique J. Valença, Jéssica Rodrigues, Daniel N. S. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Data Reports In the title β-thio­carbonyl compound, C(16)H(16)O(2)S, the carbonyl and meth­oxy O atoms are approximately coplanar [O—C—C—O torsion angle = −18.2 (5)°] and syn to each other, and the tolyl ring is orientated to lie over them. The dihedral angle between the planes of the two rings is 44.03 (16)°. In the crystal, supra­molecular chains are formed along the c axis mediated by C—H⋯O inter­actions involving methine and methyl H atoms as donors, with the carbonyl O atom accepting both bonds; these pack with no specific inter­molecular inter­actions between them. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331849/ /pubmed/25705490 http://dx.doi.org/10.1107/S205698901402550X Text en © Zukerman-Schpector et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Zukerman-Schpector, Julio
Olivato, Paulo R.
Traesel, Henrique J.
Valença, Jéssica
Rodrigues, Daniel N. S.
Tiekink, Edward R. T.
Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
title Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
title_full Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
title_fullStr Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
title_full_unstemmed Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
title_short Crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
title_sort crystal structure of 2-meth­oxy-2-[(4-methyl­phen­yl)sulfan­yl]-1-phenyl­ethan-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331849/
https://www.ncbi.nlm.nih.gov/pubmed/25705490
http://dx.doi.org/10.1107/S205698901402550X
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