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Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide
The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chlorobenzophenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benz...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331850/ https://www.ncbi.nlm.nih.gov/pubmed/25705499 http://dx.doi.org/10.1107/S2056989014026723 |
Sumario: | The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chlorobenzophenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benzene ring, respectively, with the last two rings forming a dihedral angle of 67.81 (13)°. The chlorine substituent was also found to be 0.868 (2):0.132 (2) disordered over these two rings. In the crystal, molecules are linked through pairs of N—H⋯O hydrogen bonds, giving centrosymmetric cyclic dimers [graph set R (2) (2)(8)], which are linked by weak C—H⋯O and C—H⋯Cl interactions into a chain structure which extends along the a-axis direction. |
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