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Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide
The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chlorobenzophenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benz...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331850/ https://www.ncbi.nlm.nih.gov/pubmed/25705499 http://dx.doi.org/10.1107/S2056989014026723 |
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author | Balaji, J. Prabu, S. Xavier, J. J. F. Srinivasan, P. |
author_facet | Balaji, J. Prabu, S. Xavier, J. J. F. Srinivasan, P. |
author_sort | Balaji, J. |
collection | PubMed |
description | The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chlorobenzophenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benzene ring, respectively, with the last two rings forming a dihedral angle of 67.81 (13)°. The chlorine substituent was also found to be 0.868 (2):0.132 (2) disordered over these two rings. In the crystal, molecules are linked through pairs of N—H⋯O hydrogen bonds, giving centrosymmetric cyclic dimers [graph set R (2) (2)(8)], which are linked by weak C—H⋯O and C—H⋯Cl interactions into a chain structure which extends along the a-axis direction. |
format | Online Article Text |
id | pubmed-4331850 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-43318502015-02-20 Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide Balaji, J. Prabu, S. Xavier, J. J. F. Srinivasan, P. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chlorobenzophenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benzene ring, respectively, with the last two rings forming a dihedral angle of 67.81 (13)°. The chlorine substituent was also found to be 0.868 (2):0.132 (2) disordered over these two rings. In the crystal, molecules are linked through pairs of N—H⋯O hydrogen bonds, giving centrosymmetric cyclic dimers [graph set R (2) (2)(8)], which are linked by weak C—H⋯O and C—H⋯Cl interactions into a chain structure which extends along the a-axis direction. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331850/ /pubmed/25705499 http://dx.doi.org/10.1107/S2056989014026723 Text en © Balaji et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Balaji, J. Prabu, S. Xavier, J. J. F. Srinivasan, P. Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
title | Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
title_full | Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
title_fullStr | Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
title_full_unstemmed | Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
title_short | Crystal structure of N′-[(E)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
title_sort | crystal structure of n′-[(e)-(4-chlorophenyl)(phenyl)methylidene]-4-methylbenzenesulfonohydrazide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331850/ https://www.ncbi.nlm.nih.gov/pubmed/25705499 http://dx.doi.org/10.1107/S2056989014026723 |
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