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Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide

The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chloro­benzo­phenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benz...

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Autores principales: Balaji, J., Prabu, S., Xavier, J. J. F., Srinivasan, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331850/
https://www.ncbi.nlm.nih.gov/pubmed/25705499
http://dx.doi.org/10.1107/S2056989014026723
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author Balaji, J.
Prabu, S.
Xavier, J. J. F.
Srinivasan, P.
author_facet Balaji, J.
Prabu, S.
Xavier, J. J. F.
Srinivasan, P.
author_sort Balaji, J.
collection PubMed
description The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chloro­benzo­phenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benzene ring, respectively, with the last two rings forming a dihedral angle of 67.81 (13)°. The chlorine substituent was also found to be 0.868 (2):0.132 (2) disordered over these two rings. In the crystal, mol­ecules are linked through pairs of N—H⋯O hydrogen bonds, giving centrosymmetric cyclic dimers [graph set R (2) (2)(8)], which are linked by weak C—H⋯O and C—H⋯Cl inter­actions into a chain structure which extends along the a-axis direction.
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spelling pubmed-43318502015-02-20 Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide Balaji, J. Prabu, S. Xavier, J. J. F. Srinivasan, P. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(20)H(17)ClN(2)O(2)S, was obtained by a condensation reaction between 4-chloro­benzo­phenone and tosyl hydrazide. The plane of the methyl-substituted benzene ring forms dihedral angles of 20.12 (12) and 78.43 (13)° with those of the chlorine-substituted benzene ring and the benzene ring, respectively, with the last two rings forming a dihedral angle of 67.81 (13)°. The chlorine substituent was also found to be 0.868 (2):0.132 (2) disordered over these two rings. In the crystal, mol­ecules are linked through pairs of N—H⋯O hydrogen bonds, giving centrosymmetric cyclic dimers [graph set R (2) (2)(8)], which are linked by weak C—H⋯O and C—H⋯Cl inter­actions into a chain structure which extends along the a-axis direction. International Union of Crystallography 2015-01-01 /pmc/articles/PMC4331850/ /pubmed/25705499 http://dx.doi.org/10.1107/S2056989014026723 Text en © Balaji et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Balaji, J.
Prabu, S.
Xavier, J. J. F.
Srinivasan, P.
Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
title Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_full Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_fullStr Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_full_unstemmed Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_short Crystal structure of N′-[(E)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
title_sort crystal structure of n′-[(e)-(4-chloro­phen­yl)(phen­yl)methyl­idene]-4-methyl­benzene­sulfono­hydrazide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4331850/
https://www.ncbi.nlm.nih.gov/pubmed/25705499
http://dx.doi.org/10.1107/S2056989014026723
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